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1

ChemInform Abstract: Mesoionic Carbenes: Reactions of 1,3-Diphenyltetrazol-5-ylidene with Electron-Deficient Alkenes and Synthesis and Catalytic Activities of the (Tetrazol-5-ylidene)rhodium(I) Complexes.

Shuki Araki, Keisaku Yokoi, Ryosuke Sato, Tsunehisa Hirashita, Jun-Ichiro Setsune

Journal:

Year:

2009

File:

PDF, 16 KB

2009

2

Allylindation of Cyclopropenes in Organic and Aqueous Media: Switching the Regio- and Stereoselectivity Based on the Chelation with a Hydroxyl Group and the Crystal Structure of the Cyclopropylindium Product

Shuki Araki, Fumio Shiraki, Takashi Tanaka, Hiroyuki Nakano, Kandasamy Subburaj, Tsunehisa Hirashita, Hatsuo Yamamura, Masao Kawai

Journal:

Chemistry - A European Journal

Year:

2001

Language:

english

File:

PDF, 147 KB

english, 2001

3

ChemInform Abstract: Regioselective Allylation and Alkylation of Electron-Deficient Alkenes with Organogallium and Organoindium Reagents.

Shuki Araki, Tomoaki Horie, Motoshi Kato, Tsunehisa Hirashita, Hatsuo Yamamura, Masao Kawai

Journal:

Year:

1999

File:

PDF, 35 KB

1999

4

ChemInform Abstract: Preparation of γ-Heterosubstituted Allylindium and Diindium Reagents and Their Reactions with Carbonyl Compounds.

Tsunehisa Hirashita, Toshiya Kamei, Tomoaki Horie, Hatsuo Yamamura, Masao Kawai, Shuki Araki

Journal:

Year:

1999

File:

PDF, 41 KB

1999

5

ChemInform Abstract: A New Preparative Method for Allylic Indium(III) Reagents by Reductive Transmetalation of π-Allylpalladium(II) with Indium(I) Salts.

Shuki Araki, Toshiya Kamei, Tsunehisa Hirashita, Hatsuo Yamamura, Masao Kawai

Journal:

Year:

2000

File:

PDF, 33 KB

2000

6

ChemInform Abstract: A Facile Preparation of Indium Enolates and Their Reformatsky- and Darzens-Type Reactions.

Tsunehisa Hirashita, Kenji Kinoshita, Hatsuo Yamamura, Masao Kawai, Shuki Araki

Journal:

Year:

2000

File:

PDF, 30 KB

2000

7

ChemInform Abstract: A New Cascade for the One-Pot Synthesis of Linear Homoallylic Alcohols with an Allylic Diindium Reagent.

Tsunehisa Hirashita, Hatsuo Yamamura, Masao Kawai, Shuki Araki

Journal:

Year:

2001

File:

PDF, 28 KB

2001

8

ChemInform Abstract: Allylindation of Cyclopropenes in Organic and Aqueous Media: Switching the Regio- and Stereoselectivity Based on the Chelation with a Hydroxyl Group and the Crystal Structure of the Cyclopropylindium Product.

Shuki Araki, Fumio Shiraki, Takashi Tanaka, Hiroyuki Nakano, Kandasamy Subburaj, Tsunehisa Hirashita, Hatsuo Yamamura, Masao Kawai

Journal:

Year:

2002

Language:

english

File:

PDF, 40 KB

english, 2002

9

ChemInform Abstract: Umpolung of Vinyloxiranes: Regio- and Stereoselectivity of the In/Pd-Mediated Allylation of Carbonyl Compounds.

Shuki Araki, Keiko Kameda, Jiro Tanaka, Tsunehisa Hirashita, Hatsuo Yamamura, Masao Kawai

Journal:

Year:

2002

File:

PDF, 35 KB

2002

10

Allylic-Type Diindium Reagents. Reactivity Toward Electrophiles and Cascade Coupling Reactions with Imines.

Tsunehisa Hirashita, Yousuke Hayashi, Kazuma Mitsui, Shuki Araki

Journal:

Year:

2003

File:

PDF, 269 KB

2003

11

A New Synthesis of Pyrroles by the Condensation of Cyclopropenes and Nitriles Mediated by Gallium(III) and Indium(III) Salts.

Shuki Araki, Takashi Tanaka, Shinya Toumatsu, Tsunehisa Hirashita

Journal:

Year:

2004

File:

PDF, 101 KB

2004

12

Control of Diastereoselectivity in the Crotylation and Cinnamylation of Aldehydes by the Selection of Ligands on Allylic Indium Reagents.

Tsunehisa Hirashita, Toshiya Kamei, Makoto Satake, Tomoaki Horie, Hidetaka Shimizu, Shuki Araki

Journal:

Year:

2004

File:

PDF, 203 KB

2004

13

Direct Preparation of Allylic Indium(III) Reagents from Allylic Alcohols via a Reductive Transmetalation of π-Allylnickel(II) with Indium(I) Iodide.

Tsunehisa Hirashita, Shinya Kambe, Hiromitsu Tsuji, Hideki Omori, Shuki Araki

Journal:

Year:

2004

File:

PDF, 53 KB

2004

14

Indium in Organic Synthesis

Shuki Araki, Tsunehisa Hirashita

Journal:

Year:

2004

File:

PDF, 7 KB

2004

15

Allylation of Epoxides with Allylic Indium Reagents.

Tsunehisa Hirashita, Kazuma Mitsui, Yousuke Hayashi, Shuki Araki

Journal:

Year:

2005

File:

PDF, 22 KB

2005

16

Photochemical and Radical Initiator-Induced Reaction of Allylic Indium Compounds.

Tsunehisa Hirashita, Jiro Tanaka, Ayumi Hayashi, Shuki Araki

Journal:

Year:

2005

File:

PDF, 30 KB

2005

17

ChemInform Abstract: Cyclopropanation of Electron-Deficient Alkenes with Activated Dibromomethylene Compounds Mediated by Lithium Iodide or Tetrabutylammonium Salts.

Daisuke Kawai, Katsuaki Kawasumi, Tsukasa Miyahara, Tsunehisa Hirashita, Shuki Araki

Journal:

Year:

2010

File:

PDF, 37 KB

2010

18

ChemInform Abstract: Direct Benzylation and Allylic Alkylation in High-Temperature Water Without Added Catalysts.

Tsunehisa Hirashita, Sho Kuwahara, Sota Okochi, Makoto Tsuji, Shuki Araki

Journal:

Year:

2010

File:

PDF, 42 KB

2010

19

ChemInform Abstract: Ionic Liquid-Accelerated Allylation of Carbonyl Compounds with a Catalytic Amount of Indium Generated from in situ Reduction of InCl3 with Aluminum.

Tsunehisa Hirashita, Yuki Sato, Dai Yamada, Fusako Takahashi, Shuki Araki

Journal:

Year:

2011

File:

PDF, 46 KB

2011

20

Mesoionic carbenes: Reactions of 1,3-diphenyltetrazol-5-ylidene with electron-deficient alkenes, and synthesis and catalytic activities of the (tetrazol-5-ylidene)rhodium(I) complexes

Shuki Araki, Keisaku Yokoi, Ryosuke Sato, Tsunehisa Hirashita, Jun-Ichiro Setsune

Journal:

Journal of Heterocyclic Chemistry

Year:

2009

Language:

english

File:

PDF, 298 KB

english, 2009

21

Indium-mediated reaction of 1,3-dichloro- and 1,3-dibromopropenes with carbonyl compounds. Generation of novel 3,3-diindiopropene

Shuki Araki, Tsunehisa Hirashita, Hidetaka Shimizu, Hatsuo Yamamura, Masao Kawai, Yasuo Butsugan

Journal:

Tetrahedron Letters

Year:

1996

Language:

english

File:

PDF, 170 KB

english, 1996

22

Thermal expansion of hydroxyapatite between − 100 °C and 50 °C

Hidetoshi Miyazaki, Isao Ushiroda, Daisuke Itomura, Tsunehisa Hirashita, Nobuyasu Adachi, Toshitaka Ota

Journal:

Materials Science and Engineering: C

Year:

2009

Language:

english

File:

PDF, 422 KB

english, 2009

23

Radical reactions initiated by the photochemical cleavage of carbon–indium bonds of organoindium compounds

Tsunehisa Hirashita, Ayumi Hayashi, Makoto Tsuji, Jiro Tanaka, Shuki Araki

Journal:

Year:

2008

Language:

english

File:

PDF, 504 KB

english, 2008

24

Cyclopropanation of electron-deficient alkenes with activated dibromomethylene compounds mediated by lithium iodide or tetrabutylammonium salts

Daisuke Kawai, Katsuaki Kawasumi, Tsukasa Miyahara, Tsunehisa Hirashita, Shuki Araki

Journal:

Year:

2009

Language:

english

File:

PDF, 519 KB

english, 2009

25

Reaction of indium ate complexes with allylic compounds. Controlling SN2/SN2′ selectivity by solvents

Tsunehisa Hirashita, Yousuke Hayashi, Kazuma Mitsui, Shuki Araki

Journal:

Tetrahedron Letters

Year:

2004

Language:

english

File:

PDF, 254 KB

english, 2004

26

Allylation of epoxides with allylic indium reagents

Tsunehisa Hirashita, Kazuma Mitsui, Yousuke Hayashi, Shuki Araki

Journal:

Tetrahedron Letters

Year:

2004

Language:

english

File:

PDF, 247 KB

english, 2004

27

Photochemical and radical initiator-induced reaction of allylic indium compounds

Tsunehisa Hirashita, Jiro Tanaka, Ayumi Hayashi, Shuki Araki

Journal:

Tetrahedron Letters

Year:

2005

Language:

english

File:

PDF, 276 KB

english, 2005

28

Stereoselective allylation of azirines with allylindium reagents

Tsunehisa Hirashita, Shinya Toumatsu, Yuri Imagawa, Shuki Araki, Jun-ichiro Setsune

Journal:

Tetrahedron Letters

Year:

2006

Language:

english

File:

PDF, 142 KB

english, 2006

29

GaCl3-catalyzed [4+2] annulations of allyltrimethylsilane and trimethyl(propargyl)silane with aldimines

Tsunehisa Hirashita, Daisuke Kawai, Shuki Araki

Journal:

Tetrahedron Letters

Year:

2007

Language:

english

File:

PDF, 145 KB

english, 2007

30

Allylation of methylenecyclopropanes with allylindium reagents

Tsunehisa Hirashita, Yusuke Daikoku, Hitoshi Osaki, Mamiko Ogura, Shuki Araki

Journal:

Tetrahedron Letters

Year:

2008

Language:

english

File:

PDF, 185 KB

english, 2008

31

Direct benzylation and allylic alkylation in high-temperature water without added catalysts

Tsunehisa Hirashita, Shō Kuwahara, Sota Okochi, Makoto Tsuji, Shuki Araki

Journal:

Tetrahedron Letters

Year:

2010

Language:

english

File:

PDF, 1.23 MB

english, 2010

32

High γ-selectivity in the coupling of penta-2,4-dienyl- and pent-2-en-4-ynylindium reagents with aldehydes

Tsunehisa Hirashita, Shin'ichirou Inoue, Hatsuo Yamamura, Masao Kawai, Shuki Araki

Journal:

Journal of Organometallic Chemistry

Year:

1997

Language:

english

File:

PDF, 708 KB

english, 1997

33

Stereoselective synthesis of halocyclopropanes via halogenation of cyclopropylindium reagents

Shuki Araki, Ohnishi Kenji, Fumio Shiraki, Tsunehisa Hirashita

Journal:

Tetrahedron Letters

Year:

2002

Language:

english

File:

PDF, 111 KB

english, 2002

34

Regioselective allylation and alkylation of electron-deficient alkenes with organogallium and organoindium reagents

Shuki Araki, Tomoaki Horie, Motoshi Kato, Tsunehisa Hirashita, Hatsuo Yamamura, Masao Kawai

Journal:

Tetrahedron Letters

Year:

1999

Language:

english

File:

PDF, 186 KB

english, 1999

35

Chelation-controlled regio- and stereoselective allylindation of norbornenols

Shuki Araki, Toshiya Kamei, Yukimitsu Igarashi, Tsunehisa Hirashita, Hatsuo Yamamura, Masao Kawai

Journal:

Tetrahedron Letters

Year:

1999

Language:

english

File:

PDF, 232 KB

english, 1999

36

Reaction of α-halo organoindium reagents with carbonyl compounds and electron-deficient alkenes

Shuki Araki, Tsunehisa Hirashita, Ken Shimizu, Takahiro Ikeda, Yasuo Butsugan

Journal:

Year:

1996

Language:

english

File:

PDF, 694 KB

english, 1996

37

Allylgallation of cyclopropenes. Crystal structure of a novel cyclopropylgallium compound prepared by allylgallation of hydroxy-bearing cyclopropene

Shuki Araki, Takashi Tanaka, Tsunehisa Hirashita, Jun-ichiro Setsune

Journal:

Tetrahedron Letters

Year:

2003

Language:

english

File:

PDF, 119 KB

english, 2003

38

Stereodivergent allylindation of cyclopropenes. Remarkable stereodirection and acceleration by neighbouring carboxyl and hydroxyl groups

Shuki Araki, Hiroyuki Nakano, Kandasamy Subburaj, Tsunehisa Hirashita, Kensuke Shibutani, Hatsuo Yamamura, Masao Kawai, Yasuo Butsugan

Journal:

Tetrahedron Letters

Year:

1998

Language:

english

File:

PDF, 248 KB

english, 1998

39

Fabrication of a Composite Varistor with Electrical Conductive Ni Filler and Electrostriction PNZST Matrix

Hidetoshi Miyazaki, Daisaku Tsuruzawa, Tsunehisa Hirashita, Nobuyasu Adachi, Toshitaka Ota

Journal:

Journal of the American Ceramic Society

Year:

2008

Language:

english

File:

PDF, 585 KB

english, 2008

40

Direct Preparation of Allylic Indium(III) Reagents from Allylic Alcohols via a Reductive Transmetalation of π-Allylnickel(II) with Indium(I) Iodide

Hirashita, Tsunehisa, Kambe, Shinya, Tsuji, Hiromitsu, Omori, Hideki, Araki, Shuki

Journal:

Journal of Organic Chemistry

Year:

2004

Language:

english

File:

PDF, 117 KB

english, 2004

41

Nickel-Catalyzed Indium(I)-Mediated syn-Selective Propargylation of Aldehydes

Tsunehisa Hirashita, Yuuki Suzuki, Hiromitsu Tsuji, Yoshiki Sato, Kojiro Naito, Shuki Araki

Journal:

European Journal of Organic Chemistry

Year:

2012

Language:

english

File:

PDF, 426 KB

english, 2012

42

Allylic-Type Diindium Reagents. Reactivity toward Electrophiles and Cascade Coupling Reactions with Imines †

Hirashita, Tsunehisa, Hayashi, Yousuke, Mitsui, Kazuma, Araki, Shuki

Journal:

Journal of Organic Chemistry

Year:

2003

Language:

english

File:

PDF, 93 KB

english, 2003

43

A facile preparation of indium enolates and their Reformatsky- and Darzens-type reactions

Hirashita, Tsunehisa, Kinoshita, Kenji, Yamamura, Hatsuo, Kawai, Masao, Araki, Shuki

Journal:

Journal of the Chemical Society Perkin Transactions 1

Year:

2000

Language:

english

File:

PDF, 97 KB

english, 2000

44

Control of diastereoselectivity in the crotylation and cinnamylation of aldehydes by the selection of ligands on allylic indium reagents

Hirashita, Tsunehisa, Kamei, Toshiya, Satake, Makoto, Horie, Tomoaki, Shimizu, Hidetaka, Araki, Shuki

Journal:

Organic & Biomolecular Chemistry

Year:

2003

Language:

english

File:

PDF, 120 KB

english, 2003

45

A new synthesis of pyrroles by the condensation of cyclopropenes and nitriles mediated by gallium(iii) and indium(iii) salts

Araki, Shuki, Tanaka, Takashi, Toumatsu, Shinya, Hirashita, Tsunehisa

Journal:

Organic & Biomolecular Chemistry

Year:

2003

Language:

english

File:

PDF, 132 KB

english, 2003

46

Nickel-catalysed bis-allylation of internal alkynes with triallylindium

Hirashita, Tsunehisa, Akutagawa, Kazuhiko, Kamei, Toshiya, Araki, Shuki

Journal:

Chemical Communications

Year:

2006

Language:

english

File:

PDF, 271 KB

english, 2006

47

Encyclopedia of Reagents for Organic Synthesis || Indium(III) Iodide

Hirashita, Tsunehisa

Year:

2001

Language:

english

File:

PDF, 82 KB

english, 2001

48

A New Preparative Method for Allylic Indium(III) Reagents by Reductive Transmetalation of π-Allylpalladium(II) with Indium(I) Salts

Araki, Shuki, Kamei, Toshiya, Hirashita, Tsunehisa, Yamamura, Hatsuo, Kawai, Masao

Journal:

Organic Letters

Year:

2000

Language:

english

File:

PDF, 94 KB

english, 2000

49

Preparation of γ-Heterosubstituted Allylindium and Diindium Reagents and Their Reactions with Carbonyl Compounds

Hirashita, Tsunehisa, Kamei, Toshiya, Horie, Tomoaki, Yamamura, Hatsuo, Kawai, Masao, Araki, Shuki

Journal:

Journal of Organic Chemistry

Year:

1999

Language:

english

File:

PDF, 75 KB

english, 1999

50

Umpolung of Vinyloxiranes: Regio- and Stereoselectivity of the In/Pd-Mediated Allylation of Carbonyl Compounds

Araki, Shuki, Kameda, Keiko, Tanaka, Jiro, Hirashita, Tsunehisa, Yamamura, Hatsuo, Kawai, Masao

Journal:

Journal of Organic Chemistry

Year:

2001

Language:

english

File:

PDF, 39 KB

english, 2001

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